Monster Hunter Portable 3rd HD VER

[nc50lc]

That depends on your PC, if you manage to make the controller work as NATIVE GAMEPAD using any pairing tool,. You can play using default key mappings on controls setting.
But if, you mean wireless ps3 controller for PC? Not made for ps3?= the emulator have key mapping on settings, if your controller is proven working on your PC, it can be mapped accordingly to your preferences.

I'm using my wireless ps3 controller on Android, using sixaxis app. And it works great.